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On/off controls, generally refers to your typical clock/programmer and room thermostat arrangement, where it either sends a signal saying have the heating on, or dont have the heating on. The boiler will run with a fixed target flow temperature, but will still modulate the flame size depending on how near or far it is from that flow temperature.
Take this example. The boiler can modulate its output, but is fitted with standard on/off controls.
Room at 15°C, You turn upto 20°C. Boiler fires up, with a fixed target flow temp of 75°C (very common), Way more heat than is required will be put into the rooms, so the room tempearture goes above 20°C and the thermostat will cut the demand for heating off. After a little time, the room cools, and the thermostat clicks and sends a demand for heat again, boiler fires up, aims for 75°C on the flow, room overheats, cuts off again. The "modulation" capabilities of the boiler in this case, only refer to the burner, so it will get to about 70ish and reduce the flame to try maintain 75°C in the flow pipework as that is how it has been told to run.
This description is probably about 99% of UK heating systems. (On gas boilers)