That reads as if you are confused. Modulation is where the heat created by the boiler is reduced to try to match a less than 100% demand for heat. The design of the boiler dictates how much the boiler can modulate it's output down, without having to switch off, the lower they can modulate, the better, in as much as they will need to start and stop less, which can make them more efficient.
A boiler just working on an on/off demand system, when there is demand, can only modulate down, based on it's flow thermostat.
Opentherm can improve on that, by telling the boiler to modulate down it's output, based on knowing the demand for heat has almost been met. It can also have the boiler output it's minimum output, when there is an initial call for heat, because it can predict just how much heat might be needed.
The net result is much more stable room temperatures, and some saving in gas use and wear and tear from cycling.
For example - I put my heating on at lunch time, by tweaking the room stat up by 2C, with an Opentherm type system. The boiler fired up, modulated down to it's minimum output. I have just fitted pipe thermostats to the flow and return pipes, out of curiosity. Flow got to 35C, return to 29C, as the boiler cut off completely, despite the room temperature not being quite there. 15 minutes later, the room temperature hit the 18C I had set, without the boiler firing again.
Prior to my installing my Opentherm type controls, the boiler would have fired at maximum output, until limited by the boiler flow temperature, or the stat clicking off the demand.