STAGE 2
we can rule out your expansion vessel, but not the PRV and pipework to outside
you have a Pressure Reducing Valve inside boiler that lifts at 3 bar to dump excess pressure to outside. Have a look at this pipe outside, is it dripping? are there signs its been outputting water?
if PRV and pipework are dry, you can fill boiler to 2 bar and close flow and return isolating valves under the boiler, and leave for a decent length of time (12 hrs) central heating and hot water cannot be used during this test time, boiler to be electrically isolated
if pressure on gauge down= leak from boiler
if pressure on gauge NOT down, open iso valves. if gauge drops=leak in pipework,rads,radiator valve connections
hope this helps
Sounds like a plan, thanks very much. I will try this tomorrow, should I turn the electric to the boiler off?