As to how to control the DHW not so easy, however likely you don't want it off when using CH anyway, as to how to warm up rooms faster, then using simple programmable TRV heads will do that, it is how I have done my central heating, you need some way so if all valves off water can by-pass, normal is a by-pass valve, but your DHW hot coil will do that job, the non blue tooth programmable head eQ-3 costs around £10 on internet each, and what I have done is set times so important rooms heat first, so in the morning the bedroom TRV turns on, then 15 minutes latter the kitchen turns on, and then 15 minutes latter the dinning room, and in the evening I have kitchen, dinning then living room and finally bedrooms.
Clearly you don't want the heating running 24/7 so in my case I use the hall as master control, the TRV head matches the wall thermostat so heating it turned up/down as required, I have fitted motorised valves as same heating does flat and house, but if it were not for flat, the motorised valve would not really be required, I can't turn DHW off, or control the temperature of DHW, in summer I just run for 1/2 hour 5 days a week which is about right to maintain DHW temperature.
Yes not ideal, but it would require floor boards lifting and new wires to get thermostatic control on the DHW.