Yuo will need a Wire thermocouple for the thermometer so that you can push it into the 2 pockets (where the Thermostat phials go)
The Boiler stat should stop at 82'c (adjusted by the knob on the boiler (control stat)) the store stat should delay firing of the burner on Hotwater only operation untill the the bottom pocket has reached 75'c the store stat is hidden inside the boiler control panel, you have to undow a couple of crosshead screws to release the stat, and use a fine bladed screwdriver to adfjust as necessary.
As I said this can be a very fiddly and frustrating task to get right,
after setting the boiler control to 82'c leave the boiler to settle for 10-15 mins -the boiler temperature will have reached 90-100'c by then (residual heat) then open the hot tal and watch the temperature at the bottom pocket start to fall, when it reaches 75'c the burner should fire up.