When the pump is running, the pressure at boiler return is higher than at flow, due to the boiler headloss. This tends to cause flow in the "wrong" direction through the coil. But on a big old boiler headloss won't be much, maybe only ~ 0.2m, clearly not enough to cure the problem.
Fixitflav, you might just have explained another strange behaviour i noted...
During packup, after failing to move this issue, I flick switches on the control pannel to Central Heating. This brings on a strange effect. It begins to pull water out of Flow, such that the flow pipe becomes cold very quickly, and the Reurn pipe gets boiling hot instead, though it does not get hot all the way to the cylinder. Not sure if this is the culprit.
In my next attempt, im considering opening draincock near the Boiler and letting slow escape of water from there. This would soon kick-in a slow Feed supply from the F&E Tank given the 15mm Feed pipe is actually attached to this Return pipe near the Cylinder. I then start Boiler on WATER-ONLY setting. Im hoping this top-down stream of water in the Return encourages the desired circulation in the Flow.
Could the Cylinder be at fault?
I got no issues changing the Cylinder but i know i wouldnt be able to find identical replacement. Any new will want re-routing 28mm pipes which i want to avoid.