Not sure. Most engineers said "no", because it's completely indoors, but one engineer said "yes" and replaced temperature sensors on the feed and return pipes inside the boiler casing. But I'm not sure if those sensors are for frost protection or general management of the system -- maybe both.
Anyway, today another more-senior engineer came and, for the first time, he pulled a DVM out of his toolbox and started tracing circuits and signals between the boiler, controller/timer, and zone valves. He eventually concluded that the one-year-old controller/timer is faulty, since at the time of his visit it wasn't sending a signal to switch on the upstairs heating zone when the thermostat requested it. A new unit will be fitted tomorrow, so we shall see ....