I FIXED IT!
Feel so happy.
Yes, there is no doubt that the wiring centre instructions are incomplete, in fact, incorrect.
Sometimes, we are so much into the the jungle that don't see it, you need to come out of it to see it.
As I said before, the 2 valves had 2 thermostats, if both were on, when one was turned off the valve continued to operate even though the thermostats were off. This was because of the 2 orange wires from valve. The boiler enabler was being powered by the orange wire, so even though one of the orange wire had no current, the other orange wire had current, which returned the current to the valve ,that was suppose to be turn off, as it completed the circuit for that valve. This return of current was through the grey wire which was connected to the thermostats live wire. So when
@SUNRAY Sent his diagram, it showed the organge wire being connected to the boilers live connection(grey and orange are reversible) but he was not sure how the UFh would fire the boiler as the stupid instruction didn't say. But due to this it struck me that if i connect the valve grey wires for both valves to the boilers live connection rather than thermostats live output, the reverse current from the orange wire would not go back to the valve and both valves would operate(turn off) independent of each other. and it worked. The only thing is the ufh pump and valve start together. There is no delay for the pump, i hope that is ok?
But thank you guys, thanks
@SUNRAY and
@oldbutnotdead, this definitely would not have been possible without this discussion and brainstorming with you guys. Amazing! Thanks a ton! And I feel obliged.