The old receiver uses Opentherm. A Hive receiver does not.
With the mains power to the boiler switched off:
Disconnect the old receiver wires, and either link the two Opentherm +- wires together, or buy the link plug which does the same thing.
The Hive receiver connects to LNE for power, and the other two switched connections go where the red link is in the 'thermostat' terminals as in the original photo.
Buying another opentherm receiver might save you 1% on your gas bill assuming it works properly with your boiler, which it probably won't.
All the rest about TRVs is unrelated and irrelevant.
With the mains power to the boiler switched off:
Disconnect the old receiver wires, and either link the two Opentherm +- wires together, or buy the link plug which does the same thing.
The Hive receiver connects to LNE for power, and the other two switched connections go where the red link is in the 'thermostat' terminals as in the original photo.
Buying another opentherm receiver might save you 1% on your gas bill assuming it works properly with your boiler, which it probably won't.
All the rest about TRVs is unrelated and irrelevant.