EPL I think do thermostats designed to work as master/slave so multi-thermostats control one boiler, think limit is 10. The thermostat has duel outputs, hard wired to the motorised valves and I think wifi thermostat to thermostat and master hard wired to boiler OpenTherm control. I only know of the one make which can do this.
Drayton Wiser do a three channel thermostat, but in the main using motorised valves like this
today is old hat, as most gas boilers use the return water temperature to control output, so electronic heads on the TRV is the method used today, these
are clearly motorised valves, the exception is UFH where these
seem common, I would say your first job is to decide how to progress.
There are special TRV heads designed to work with Hive, the problem with the TRV control is it can't turn on a boiler when required without water flowing, so would need to cycle on/off all the time to know when needed. So having a wall thermostat in a down stairs room with not alternative heating, and no out side door, normally kept cool means boiler does not need to cycle.
Whole idea of Hive is as long as under 22°C TRV heads can send a demand for heat so keep boiler running even it the room it is in is warm enough. And to be fair it seems a good idea.
No domestic system seems to be all singing and dancing, each has good and bad points, and it seems hard to work out what they all do. Some times wonder if best option is blind fold and stick in a pin.
But the big thing is the home, mothers house hall always coldest room wall thermostat in that room worked well, last house no hall, open plan, and thermostat between living room and dinning room close to arch between the two also worked well, this house hall in centre of house, and is last room to cool, and I have realised it was not best location for wall thermostat. And my first house was hot air central heating and did not really matter where the thermostat was.
What I am saying there is no one system suits all.