Here, here to that....
....but why didn't you just observe the valve opening when the thermostat was calling for heat? You could have seen the lever operate the (Honeywell V3) microswitch and observed that the boiler wasn't called (240v on the orange wire COMPARED to the neutral blue wire). You could even have poked an insulated plastic 'prodder' in to operate the microswitch, again to test its output is as expected. All this talk of 240v on the blue wire created a red herring, and two needless pages of discussion. Having said that, I'm glad you got it working again.
MM