I thought he meant the header tank, he also says it is continuously overflowing.
If overflow level is above float valve it could be a stuck float valve which he cannot see.
Hot water could just be overpumping possibly made worse by elevated level and expansion pipe not high enough.
You could try a magnet on the pipework to test , magnetite is magnetic so a pulling magnet would indicate a blockage.No good for detecting limescale though.
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