That will look odd! If I was desperately bothered I'd hack off a bit of brickwork either side (lintel bearing withstanding) - a bit of messy work with chain drilling and chisel but surely a better result.
I reckon that's the most pragmatic solution, which in my experience will be accepted by most BCOs, as the alternative is pretty impracticalMaybe this with 9.5mm plasterboard?
10mm XPS Premium Insulation Board
https://www.amazon.co.uk/dp/B009A826Y6/ref=cm_sw_r_cp_apa_i_g5OxFb1WSYY63
they’re thermaline. i was referring to fruitybum as scholar.It's ordered. To clarify, in the pic is 25mm insulation and 9.5mm plasterboard, so 34.5mm total. So those thermaline scholar boards will be no good.
I think I had this dilemma in another room and ended up just spraying the dryfix foam on thick ... will leave the top as it is (did like this in new bathroom window it it looks OK) but replace the sides with 10mm insulation, giving an extra 15mm minus skim and adhesive.
Are you using angle beads, the last ones I bought from Wickes are around 20mm (From memory) I stapled them on.
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