Why don't you just change the head of the PRV
Lost count how many Ive done, works everytime
There is a knack to it, but is much easier than changing the complete lot
Standard caleffi safety valve
Just squeeze the head, close to where it screws into the brass body, squeeze tight onto the small black plastic rim, and turn anti clockwise. This removes the head, sometimes, you have to poke your little finger in to remove the black rubber washer, and change it for a Worcester caleffi head (different body, exactly the same head once unscrewed.)
As for the expansion vessel, piece of cake to change, just make sure that the diaphragm is definitely persihed, and the vessel doesn't just need repressurising, or I've had it the once, on a Response, where the flexible connector is blocked/kinked. This can easily be verified by opening the PRV by turning the head to depressurise completely, and by pumping up the expansion vessel, if water is displaced (i.e. you hear water coming out when you are pumping up the vessel), then the flexible braided tube is ok.
The bottom connection on the expansion vessel can be awkward to get to, but is much easier to remove with a basin wrench, and remember to change the 15mm fibre washer. The expansion vessel comes out by removing the small plate (on the top of the boiler case) above the expansion vessel and cracking the union on the 15mm union on the bottom. Sometimes, there is also a screw on a swivel plate that holds it in. Should take no more than 20-25 minutes to do the expansion vessel and PRV. When taking the bottom plate off to get to the PRV, don't remove the middle screws, as these hold a right angled plate with the electrical connections on and can be difficult to get on afterwards.
Any problems post again