Basically 5k would be for heat pumps, 10k for standard efficiency boilers, and 20k for condensing boilers.
However, that assumes the heating system has been specifically designed for one of these temperature differences, which very very few have (actually been designed that is)
The next issue you face is do you have more than 5 radiators? if so its a bit of a pointless exercise as you will then have uncontrolled flow rates through the non-flow regulated radiators which will alter the Delta T at the heat source so making the purchase of the new valves a little pointless.
Last issue is, that unless the boiler is the exact size for your system (ie not a combi) then the chances are that if you did set the system up with the exact flow rates that you would expect, then most of the flow will need to bypass to the return, heating the return before it re-enters the boilers heat exchanger, which in the case of condensing boilers will drop the efficiency.
I tried the eclipse valves as an experiment a few years ago, and removed them. Don't get me wrong, they do the job wonderfully, they will maintain an pretty exact flow of water across a radiator with surprising accuracy (although I found them to be rather audible) however is that whats best for your system? balancing via strangulation of radiator flow is not the correct way to balance a system for efficiency, if efficiecny is the primary goal then you need to be very carefull how you go about it, as most gimmicks and products are no match against actually knowing how to set a heating system properly.