I've heard this theory from scale reducer manufacturers as well. "The electromagnetic field disturbs the calcium molecules so that although the calcium still exists, it does not stick to metal".
I have worked in electronics R&D labs for more years than I care to put on my CV, and done a lot of work with coils, their inductance at various frequencies, their magnetic fields, EMC testing and so on. I suppose the idea that the scale reducer manufacturers would like to con you into believing is that rattling the chalk molecules at 50Hz is going to make them dizzy so they don't know that they were supposed to stick to copper or steel or aluminium any more. It has to be at 50Hz because there is no active electronics in them to make them work at any other frequency. The theory that "once the water is released to atmosphere it will revert back to its original condition so testing it may be dificult" shows their lack of knowledge of an open vented heating system. Exactly what do they think is in the tanks in the loft then? An army of fairies defending the "scale-reduced" water from the ravages of the atmosphere?
Sounds like another salesman's boiled tripe to me, like Dyson's false statement on his TV adverts. "Never ever loses suction". What a load of old toss. If they never ever lose suction, how come I find loads of his products at the tip (sorry, that should read 'recycling center') every time I go there. There they are resplendent in their multi-coloured glory, not sucking. And that's not because they are no longer plugged into a 230v supply, either. They are broke. They don't suck any more.
I know a few things about how Sinclair started his fortune-making business that most people don't. In my opinion, caveat caveat, he should be in jail instead of kneeling in front of the Queen, caveat caveat (cos he's richer than me!). In about 1966/67 he bought scrap transistors from Plessey in Swindon (fact) and sold them to budding electronics constructors having convinced them that they could make a working ten transistor amplifier. They didn't work. Fact. Still, he's rich and I'm not. So who won then?