why not fit two boilers one in each kitchen and split hot water and CH between the two and something to fall back on if one breaks down, since you have two kitchens and two baths, and so on. Decide how best to split the two if you decide to split the house in two 3 bed houses. (only a suggestion)
Maybe I could. Good idea, my brother had two in his building and i saw it work well. For commercial situation it is a clever idea. But in this ( domestic ) case it's too expensive (I think).
1) I'll have to pay for the second boiler my self, don't want to do that... Plus it might mean two lots of things to maintain and insure in the house. Even more expense.
2) don't have anywhere to put it, unless I loose a cabinet, which I don't want.
3) will require a lot more work, thought and maybe an overkill
4) the 28si II combi (about 80% efficient and D rated!) was doing well till now (except for hot water at some short times during the day). At only about 28kw ~ 10.3 L/min. I can see why.
An upgrade to 32cdi (90.5% efficient and A rated) = 32kw = 13.1 L/min or better still 38kw = 16.4 L/min, I feel may do the trick.
The si is a different model and different efficiency to the Cdi. I have the si II model but the Cdi at the same rating seems to give pound for better hot water flow rate.