Will answer your questions first, but before doing so, will say in a very kind way, if you do not know what a purlin and rafter are, then I do not fancy your chances of pitching this roof on your own.
Rafter is the timber member that forms the slope on roof and supports felt, battens and tiles. It will pitch from the lower wall plate on the back skin of the back wall on new extension to the top wall plate fixed to your existing house.
Purlin is a large timber member that runs at right angles to your rafters and sits on the gable walls and supports your rafters either mid span or 1/3 and 2/3 span. The purlin enables you to reduce depth of rafters to make roof more economical to construct.
C16 and C24 are the new European grades for grading carcassing timber. All timber is graded usually at its point of origin to determine the strength. It is either done visual, mechanically or by species, and should then be stamped on timber. C24 is the strongest, but often difficult to obtain.
Was now going to tell you how to get round the binder problem, but have sat here thinking and have come to the conclusion that this roof is going to cost you a fortune, even if you can do it.
Have phoned Minerva Truss Co to-day 01978 758869, and they said it will be no problem to make you up Mono half trusses with a stub toe to build in at 600 centres. Believe me this will save you a lot money, and you can easily throw them up yourself. Strongly suggest you go this route and if you want any further help at all on how to fix trusses then come back. Google roof trusses then Minerva.
oldun