The pressure drop happened very suddenly. The heating had been fine for over 2 years, then one day, I noticed a gurgling in the rads, so bled them, repressurised and then within a 24 hour period, pressure was at zero. No visible water was coming out of the overflow pipe - or anywhere else for that matter - so I called my original plumber who did various things, including turning the red tank (don't know what this is called!!) up the right way as it had been fitted upside down. This made no difference. Leak sealant was put into the system, which had little/no effect. During the summer, I noticed that loads of water was now coming out of the overflow pipe, so I told BG and they came out and I will list below what they have done (you may need to interpret this as I am copying from their handwriting!)
01/12 Pumped up both expansion vessel, red and white. Replaced valve on white expansion vessel.
At this point, even more water started coming out the overflow, and pressure still dropping, so I called again...
08/12 Condensate checked and no signs of excessive water. Checked expansion vessel; Refitted C/H zone(?) valve due to not fitted to body properly. No change in pressure during visit (with me for 2-3 hours)
Obviously, as soon as he left (within about 30 minutes) the pressure dropped to zero. So the next day, someone else came out...
09/12 Deconnected condensate under boiler - left off. Turned off boiler
At this point I was left for 24 hours with an icecream tub under the disconnected pipe behind the boiler. After an hour, pressure was at zero, and no water in the tub. Hea came back the next day to reconnect.
At this point, I think they called in Dynorod - who came 3 times. They couldn't spot anything. So the independents were called in - Polygon. They couldn't find anything with thermal or sonar equipment. However, he did find what he considered to be an excessive amount of water coming through the condensate pipe - but this was while the heating was on (which I believe makes a difference), and it didn't dribble out, but it was expelled at about a pint or so each time. He also found, under my kitchen cabinets, a lot of condensation dripping from the pipes. He then reported back that it could be a problem with the heat exchanger and said that it needed to be checked and sent in photos of water pouring out of the condensate pipe. At which point BG came in and changed the heat exchanger. To no effect. Polygon then came back to do the gas tracer. They pressured the system to 1 bar for over an hour and no gas escaped. The only thing he did say is that this test is done when the pipes are cold, and it is within the realms of possibility that the water escapes as the copper pipes expand and contract. Over the summer when the heating was off and I only had the hot water on, I did lose pressure but it took around 3 days for it to go from 1.5bar to zero. Definitely, most water is lost as the system cools. I really hope I haven't bored you all too much!