I had a similar problem recently. The expansion PRV was leaking. I took it off and tested it, and found it opened at it's set pressure of 8 bar. This was on a new combination valve. I changed the expansion valve, having tested the new one, and exactly the same thing happened. I don't know how I cured it, but with a couple of times opening the valve, it eventually stopped leaking.
If anyone knows the answer I'm interested.
If anyone knows the answer I'm interested.