My son had this with a Worcester Bosch boiler, and it turned out to simply be the lock shield valves that needed setting.
Once to temperature the TRV's will control the flow through each radiator, however while heating up the lock shield valves control the flow, so if left wide open, it will heat up one radiator at a time, starting with the easiest for water to circulate through, and only when the TRV starts to close will the water be pushed through next easiest radiator.
Simple test, is the return water hot, if so the lock shields need setting. The basic idea is there should be around 15ºC temperature drop on each radiator when the TRV is wide open, but not an exact figure, so what I did was use the info from the TRV heads,
if the current exceeds the target then the lock shield needs closing a little, used this method at late mothers house and once set the TRV's kept the rooms spot on.
The problem is how a boiler works has changed, in the old days returning hot water did not really matter, it only turned the boiler off when it reached a set limit, but today boilers well at least gas, modulate that means turn down, so the warmer the return water the lower the flame hight.
So my old house has Myson fan assisted radiator in living room, this had no lock shield valve, output was controlled by turning fan on/off rather than regulating the flow, great system no need for geofencing and the like, as could heat living room from cold to 20°C in half an hour, with a 4.5kW gas fire, 3.5kW fan assisted radiator and a 4kW conventional radiator. But when my son had the two boilers removed and a combi boiler replace them both, he had to modify the old Myson, and needed to restrict the flow, he also added a thermostat across the resistor for speed control, so now works two speed, not quite as good as new Myson iVector which has a 5 speed fan, but an improvement on old system as high speed only used when room very cold.
But I know when I went to live with my mother to look after her, I found every lock shield valve wide open, I suspect the installers never set them to start with, but my dad could have opened them.