DP - on the baxi model mentioned in the OP's post, there is only one connection of the expansion vessel to the radiator circuit, therefore only one way "in" for the water. The schrader valve is open to atmosphere, with no connection to anything else. So I have a failure to see where water in the "air" side could come from. It's a direct copper pipe connection to the expansion vessel from the radiator circuit. BUT, thanks for info.
I for one will NEVER say that I an right every time and can fix EVERY boiler every time. Come here to learn
Having said this, Re expansion vessel, how do you know the membrane dividing the air and water is not permeable to allows microscopic amount of water to permeate to air side. Seen this happen on brand new vessels after a few weeks. Granted such a vessel could be defective out of factory but surely not almost every vessel on one particular boiler
A regular, who is also an instructor, person of vast knowledge, concedes that a vessel with water air side need not be goosed- let the water and air out while system is at working pressure until air side is empty, then pressurise to working pressure with primary at zero pressure.
I too will thank you for educating me on make up of expansion vessel, how it works etc. I have been in the dark for thirty years, light has been switched on with your explanation on construction of this rocket surgery component