The pump should be wired to the boiler, so the boiler puts the pump on whenever it's on itself, and for a while afterwards for cooling. So if boiler on and pump not on, pcb faulty.
WHat's on the grey wires, they should both be connected to Live.
The two orange wires from the 2 2 port valves will be connected together, so separate them and reconnect the CH one for tests. What's the voltage on the grey wire, which should be 230vac too. The grey and orange wires are only connected together by a simple switch when the valve is open - hard to see where 180v comes from unless there's a wiring error.
WHat's on the grey wires, they should both be connected to Live.
The two orange wires from the 2 2 port valves will be connected together, so separate them and reconnect the CH one for tests. What's the voltage on the grey wire, which should be 230vac too. The grey and orange wires are only connected together by a simple switch when the valve is open - hard to see where 180v comes from unless there's a wiring error.