To get back to the subject, as for system size, I said in the first post the system was 4 rads.
The pressure at start was 1 bar air, 1bar water. The system gauge was approximately right.
I take it from the trivial replies that no one can offer an explanation based on experience.
Indeed oilman, it seems very odd.
12 litre ev seems more than adequate, and as it is new and charged we should be able to rule out it is the culprit.
You probably checked, but have to eliminate all options; did the pressure go back down when the system cools off?
Could it be that there is something that contains a lot of water that is connected to the system which causes the unexplained pressure rise?