when the rad was flushed out this was clean also.
Sludge can be hard to dislodge!
Did you turn the rad upside down? If you don't, the water can easily travel straight along the bottom of the rad and miss all the sludge trapped in the water ways. A rubber mallet to 'tap' (fairly hard) the rad will also help shifting the sludge.
As for balancing, here's the quick way:
1. Remove all TRV heads and set all wheel valves to fully open.
2. Set all lockshield valves to 1/3 of a turn open from closed (fully clockwise).
3. Start boiler and allow system to warm up
4. Feel all return pipes (cooler one) to see how warm they are.
5. Select one which is midway between the hottest and coldest and use it as a 'standard'.
6. Any rad with a hotter return than the 'standard' should have the LS valve closed a tiny fraction.
7. Any rad with a cooler return should be open a tiny fraction.
8. Repeat 4 to 7 until all returns are approximately the same temperature.
Do no expect perfection. The adjustment each time is very small and you need to leave time (say 10 mins) between each cycle for the system to settle down.
When finished replace all TRV heads and set to required temperature. Set all wheel valves to required position.