OP,
Ignore, in fact run a mile from, user name bennymultifinish. Most everything he has said is wrong. He knows nothing about these matters. In a word he's not only ignorant but obliviously ignorant of the foolish stuff he pretends to know.
All the plaster has to come off - no matter what.
His adventure into chemistry is a case of wrong, wrong, wrong.
He doesn't even know what glaringly obvious CWI injection holes would look like.
You dont sit flue vents on top of the skirting for a very good reason.
You have a couple of flues running up past the the next bedroom(?) - what's the condition of the plastered walls in there?
catlad is quite right about dropping the stack a few courses.
Appropriate terminals should be fitted as required.