Yup, I think it was my fault to be honest. It was a relatively new thermostat, so it would have had plenty of life left in it, but because I didn't bleed the air out of the system properly, the plastic probably melted and weakened...and snapped! I found a great method of filling the system eventually, blowing into the expansion tank! It worked a charm, system took more or less it's full capacity on the first go. Used both bleed valves, heater pipe and thermostat housing. Sadly, the bolt or thread in the thermostat bleed hole it all rusty inside, and the bolt wouldn't fully tighten when I tried to nip it up, is it OK to use thread lock on these, or is there anything else you could recommend?