A smart TRV is a zone stat; I would call it a comfort feature not an efficiency feature unless it has an influence on the boiler operating temperature.
The very best efficiency is provided by a properly integrated to the boiler control system, providing feedback to the boiler, so the boiler is aware of the amount of demand it needs to meet - rather than an demand/no demand, on/or off control system. A smart TRV, like the Hive only provides that on/off control. They provide an extra complication and expense for very little improvement in performance, if you already have normal TRV's fitted.