Your boiler has to support PDHW and you will need to have a normally open 2 port valve on the heating circuit. There will then need to be some wiring changes in the wiring centre.
I think this is the sort of set up being referred to by Madrab. This is a wiring diagram for EPH controls for PDHW on an OT boiler, even if the boiler doesn't have native support for PDHW. As far as I understand it, when the Hot Water Receiver fires, it sends a signal from port 1 to the Heating Receiver port 2, which turns off the heating. Full explanation and further diagrams at link. I've only found this layout from EPH so far. It uses the standard S-Plan valve layout AFAIK.
If you need to find a tradesperson to get your job done, please try our local search below,
or if you are doing it yourself you can find suppliers local to you.
Select the supplier or trade you require, enter your location to begin your search.
Please select a service and enter a location to continue...
Are you a trade or supplier? You can create your listing free at DIYnot Local