No, a TRV will restrict the flow, when the room is up to temperature, so the water contained in the radiator, will be cooler. The cooler it is in the radiator, the cooler the outflow, the cooler at the return to the boiler.
In that case, it would seem that you're talking about something rather different from what is usually said in relation to 'over-sizing' radiators - since the whole idea of what is usually said is to allow the flow temp to be reduced (from a historical delta T 50 down to delta T 30, or even 20), which obviously also reduces the return temp, improving/facilitating condensation.
However, with that approach, although it might be 'over-sizing' in terms of physical dimensions, it may not be in terms of heat output, since that obviously falls when one reduces flow temp. In other words, a physically larger radiator is used to facilitate a lower flow temp whilst giving as much heat output as a smaller one would with a higher flow temp.
One issue with that approach is presumably that, if flow temp is going to be reduced, the 'over-sizing' has to happen with all rads in the system - since, if not, those that have not been 'over-sized' will probably not produce enough heat (with the reduced flow temp).
... but that begs a question, to which I don't know the answer (but am about to try to find!). I am used to naively just 'accepting' the 'power outputs quoted for radiators of a particular size, without actually having any idea what flow temp (i,e. which 'delta T') those figures actually relate to.