I would be inclined to use your 100mm Kingspan solid up against the deck held in place with battens or nails and then fill the void with a couple of layers of Rockwool or similar. Use a foil backed board.
Yes John but this how many a garage conversion roof is done and the timbers do not seemingly rot, as mentioned not ideal but OK.I'm still not comfortable with trying to make it unventilated. Poking insulation up from below is never going to make an airtight seal that prevents warm humid air reaching the underside of the decking boards. But stuffing it is going to prevent ventilation with cool dry air from outside.
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