I never actually thought about it before, but the installation certificate should be with the consumer unit, so it is possible the installation certificate does fully identify circuits, however the labels used on the consumer unit are the standard issued ones with consumer unit just giving a quick reference to if lights or sockets.
The Martindale proving unit I found useless as it only gives out 500 volt, so one could get a faulty tester which will only light with 500 volt and not with 230 volt, unlikely I know but the whole idea of a proving unit is to prove the tester works, other makes like the Kewtech have a ram up and step down so will show if the 12 volt lamp will only light with 500 volt, Megger also rams up and down with lights to show the voltage being tested.
And even with the best testers they can't stop it being re-energised after the test has been completed, I had it once with a concrete batching plant, a new plant had replaced the old one, but cables had not been removed, it was my job to remove them, I found a junction box which the old electrician identified as being part of old plant, no lid on the box and open terminals so one would hope it was dead, however just in case I tested every cable, before starting to saw off the cables and remove them.
I left to have my dinner and got called back with reports one cable was sparking, it transpired it feed an augur which was still in use and had not been replace when new batching plant was installed, this was auto switched on by the PLC running the batcher. So there was no way any testing for dead would have found this, after that near miss cables were only removed when the batching plant was not running.
The same applies with a domestic house with items like the central heating, cables supplying motorised valves may only be energised when there is a call for heat. This is why I still use a neon screwdriver, not to test for dead, but to alert if power should get switched on again. With high voltage not only do we prove dead we also ground the cables so they can't become live latter. However we rarely go to those lengths with the low voltage used in a house.