In reply to olski..."Just to make sure, your running water was definitely coming out of the expansion pipe for the F&E tank and not the cold water storage tank ..."
Dont know what F&E stands for, but the water was being pumped up the expansion pipe (the vent pipe), and entered the cold water storage tank from above the lid of the tank. The cold water tank i mean is the one that replenishes the cold water that you use when you have a bath for example. It is the larger of the two tanks, the other cold water tank, which is much smaller is is the one that keeps the boiler circuit replenished with water.
As far as i know, there is no way to inspect the possibilty of a corroded heat exchanger. In my case, the internal pipe got damaged when the flange nut was tightened because it was leaking. It cured the leak, but unbeknown to me, it precipitated this horrendous problem which came to light several weeks later, and no one had a clue what could be wrong. By rights, i would have also expected contamination of the hot water supply, but there was none, and i presume the leak must have started slowly, removing slowly over weeks the contamination.
Perhaps one way tofind out would be to introduce a dye into the boiler circuit and see if it appears in the hot water system.