Problem with putting silicone on the underside washer is that it can either expand or slip sideways as you tighten things up and you end up with a serious leak. (Been there, done it )
Have to say I've never had that happen. The silicon would be around the gap as opposed to the whole of the washer.
to be sure is it possible to use silicone inside bath with no washer as already said ,tighten up with the back washer & screw tight ,then as i am in no hurry after 24 hours unscrew & do the back of bath , would this work or a bad idea