Any sparky able to tell him :
1. if he can connect another twin and earth cable to the existing ceiling rose to create another ceiling rose in the new room?
2. the size cable he needs to buy?
3. How using a multimeter would help him identify and remove the switches?
I am sure he wanted a bit more than "it's not complex"
Unfortunately Matt I am not a sparky and cannot therefore help as I may give incorrect advice.
But if I were doing the job, I would first identify the switch cables.
This post might be helpful :
//www.diynot.com/forums/viewtopic.php?t=200734
This thread is for a single (NOT two way switch - your switch will contain THREE CORE AND EARTH cables not TWIN AND EARTH - assuming the two switches you refer to operate the same ceiling rose - but the thread is helpful, because it shows you what you now want to achieve rather than what you may have with your two way switching). So I would remove all of the existing switch wires from the switch to the ceiling rose and replace with twin an earth from the switch you wish to use for the existing light and install new twin and earth cable in the other switch which will operate the new ceiling rose you will be installing.
You should only need a multimeter if you forget which wires are the switch wires after disconnecting. The ceiling rose should tell you which is the switch wires.
A sparky might be kind enough to tell you if you can use the existing three core and earth switch wires without replacing it - if it is possible.
In the picture from RF Lighting, he is using some OLD coloured cable - you might see Brown for Red and Blue for black - but it neatly shows you how a typical ceiling rose and switch is wired.
That's what you need to aim for in the existing ceiling rose and the new one you wish to install.
In respect of the new one - I would "suspect" it would be alright to "spur off" the existing ceiling rose to create a new ceiling rose by using 1mm Twin and earth cable - that is connect a new cable to the existing ceiling rose to the existing Live, Neutral and Earth, so you have an additional cable in the ceiling rose (it might get a bit busy). A sparky should confirm this.
From the new ceiling rose, you need to achieve the same set up as the picture from RF Lighting I have referred to, but this time the new ceiling rose will not be supplying an additional ceiling rose, so will contain one less wire.
The key thing for you is to identify the switch wires and main circuit wires.
Please check before doing any work.