The installation manual you have gives you all the information you need. Without following the wiring diagram with a multimeter, it is impossible to diagnose the problem. The programmer you have fitted is not the original, but a version of the same unit that performs the same, but is not rated for the temperature it is operating in. Consequently they fail prematurely, yours may have. Which programmable room thermostat do you have? This may have been installed incorrectly.
You should be running with the Stanley in HW and CH mode, with the CH slider in the constant position but if the thermostat has been installed incorrectly, you may have a constant feed to the CH valve. Probably a job for an experienced controls technician.
You should be running with the Stanley in HW and CH mode, with the CH slider in the constant position but if the thermostat has been installed incorrectly, you may have a constant feed to the CH valve. Probably a job for an experienced controls technician.