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EddieM
First - put all the other nuts back on!!!
There is now 1 single nut taking a lot of tension. Use the other 4 to relieve that tension and the 5th will come off. It's "Fitting 1.01". Just like when you torque them up afterwards, you wouldn't just bust in and do one up to full tension, would you. WOULD YOU?
Second - having the full weight of the car on the ground is fine to slacken the nuts, but also recall the above - it means the whole weight of the car is now acting through one lug nut alone. Chock it FIRMLY, stick it in gear, stick the handbrake on, jack it up a little to take the weight off the hub, if only a little. Problem with this are two fold - might not be enough friction on the handbrake (if dealing with rear wheels of FWD car) and most major - you might pull the car off the jack if it's up too high and the chocks are loose. (This can also happen through driving the other wheel opposite direction through the diff)
Nozzle
Maybe... but deffo the advice of turn the wheel in