All sounds fine. Even with boiler on 1 pipework will be too hot to touch unless you are in the trade. Only thing is once cylinder is up to temp then it will all go off again so remove stat from cylinder if you can or take it in turns to have a bath. To confirm to yourself, can you get your hands on the 2 pipes as they leave the boiler? Flow should obviously be quite hot and return cooler but gradually you should be able to feel temperature increase confirming circulation. No need to but if you get nervous you can turn boiler to off on the stat and you will feel the flow cooling as remaining heat is dissipated.