Not for that model of boiler no, the CDI classic regular has simple on and off controls - Switched Live - it doesn't have an E-Bus, which these days is a Open Therm or WB's EMS (BB). Without an E-Bus and the extended sensors/PCB control etc, the smart controls cannot control the system temps in the way you want. Sounds like you may have been sold the last one of that model on the shelf I'm afraid.
If maximising efficiency is important then the system needs to be balanced properly so the desired drop in temps across the rads can be achieved ensuring the return temp is as low as possible and maximise condensing. When it comes to HW then 55Deg as a standard with one day a week up to >60Deg, if legionella is at all a concern, though it shouldn't be for a well maintained regularly used HW cylinder. Under those conditions then a return temp of 50Deg should be achievable, which is well within the boilers condensing range.