Beware- your new controller may not be suitable for your setup.
At the moment you have L and N powering the thermostat and volt-free contacts connecting 1 and 3 when heat is required. Lines 1 and 3 might not be 240 volt, some boilers use an extra low voltage for that function.
Your new toy uses the L supply to the stat for signalling as well as power. More info needed- pics of the terminations at the boiler or wiring centre would be useful, as would make/model of boiler, are there motorised valves, that sort of stuff