Oh dear , seems the Bunny boys stumbled upon this thread after all.
Take heed JSHarris , two of the best vaillant guys in the business (831/bunnyman) have taken the trouble to reply to your thread , LEARN something from it.
Look, I have learned from it. In fact I learned from the advice given freely here a year ago and as a result the chap that is now looking after this boiler for me fixed the system, such that we've not seen an F.75 fault once in the past year. That problem is fixed, completely and 100% fixed. It's a non-problem now, and when the boiler is running the system works extremely well indeed.
The current problem is wholly un-associated with the pressure sensor and the blasted F.75 fault code. It seems to be something within the PCB that causes the boiler to continue to run the CH even when the programmer/thermostat is satisfied and even when the diagnostics are showing that the thermostat is satisfied. It also does the converse, in that the boiler will stay off even when the programmer/thermostat is calling for heat, and when the diagnostics indicate that this is so (d.8 = 1).
I can temporarily fix the fault by turning the power off, waithing five to ten minutes, then turning the power back on, which will often resolve the fault for maybe an hour or so. Unfortunately, ths fix doesn't last much longer than this, although when it happened last year turning the boiler off, waiting a while, then turning it back on, did fix the problem for the whole heating season.
I've got a new PCB on order, as based on what's been advised here and my own gut instinct I suspect that the fault must be within the PCB.