Ok right so, I dialed the rising main down to a less powerful flow as an experiment, so these figures are based on the reduced flow due to that:
Kitchen 6.5l/m flow rate, 13deg cold, 54deg hot
Bath 7.3l/m flow rate, 43deg hot.
I see the higher flow rate means it will be colder, but both flow rates are well within the 12.4 flow rate the boiler is rated at.
With the bath at 43deg, it would need a bit of cold added, but at that flow rate would also take hrs to fill!
Oh and the boiler is 30kw for dhw, rather than the 24kw I stated earlier.