If the unvented is the other side of the wall probably not a lot, but it gives you 24/7 hot water without draining the cylinder, meaning you have more hot water available for bathrooms and can use a smaller cylinder if space is a premium.
Connected my daughters that way, the boiler is about 3 feet from the sink/utility whereas the cylinder is the other side of the house, so she'd waste gallons of hot water every time she uses the sink
Connected my daughters that way, the boiler is about 3 feet from the sink/utility whereas the cylinder is the other side of the house, so she'd waste gallons of hot water every time she uses the sink