Yes, that seems correct.
If you have a go at the wiring, post some pictures here, and we can confirm, before you turn the power back on!
However, just removing the black wire isn't enough - if you don't do any further modifications to the wiring, it will still be a switched live wire from your existing thermostat - park it safely in one of the spare terminals on the left of the wiring centre.
If you can also trace the brown wire from that same cable, you can park that in a spare terminal.
That should, theoretically, decommission the mains cables to your old thermostat.
Is your existing thermostat battery operated? - the grey wires from the cable are already isolated in the terminal, second from the right.
You mention ebus, but we don't know if your existing thermostats use it. There is definitely a switched live, back to your boiler from the wiring centre.
Can we have a peep behind your existing stats to confirm?
Far more likely to be a combi with dual zone heating on a new-build, built after 2014, with that wiring centre.
yes it is a new build I can't get behind the room stats but think I will be all good now thank you so much