Hi all, sorry for late reply, I think I can now safely say that one of the micro switches in the valve has failed, likely the one that links the white and the orange.
Just to clear a few things up, when I was measuring the voltage, The probe was on orange and (blue) neutral then earth, I get 85-90v, however this still activated boiler. I temporary put the pump live back to the demand terminal, which has orange,blue (cylinder stat call) and boiler switch live, neither the pump or the boiler switched on at all, I waited about 10 seconds to give the valve time to move but nothing, when I measured the voltage between demand neutral and earth there wasn't any.
just thought I would give you an update
Can this be fixed without changing the valve or head?
thanks