I would consider changing the valve to a Honeywell. The Sunvic valves dont seem to last very long, as I found out....
Afraid it gets quite complicated. When HW is called for alone the boiler is supplied with power from the cylinder stat. The valve does not play an active role.
If CH is also called for while HW is still called for, the room stat supplies power to the valves white wire. This powers the motor until microswitch is triggered at mid position. There is no power on the 'grey' or 'yellow' in your case, so the valve stays at mid position. Boiler still being supplied power from cyinder stat.
When HW is satisfied (or turned off) the cylinder stat is out of action in supplying power. Two actions are required for the sysytem to continue.
First the valve must move from mid position to CH only and power must be supplied to the boiler.
The cylinder stat is of a two mode, so power that was going to boiler is diverted to the valves 'grey' and when this is live it takes over from the white and moves the valve over the final stage. This diversion wont work if HW was never on, so alternative is introduced coming direct from the programmers HW switch (another two way). The wire coming from the OFF terminal. It does not matter if this wire is fixed direct to the valves 'grey' or the cylinder stat terminal fixed to the 'grey'.
During the valves travel over this stage a 2nd microswitch is triggered which allows power supplied from the room stat out through the valves 'orange' wire to power the boiler.
The usual problems associated with 3 ports are (a) the valve not moving beyond mid position or (b) it does move correctly but boiler fails to light
I think, but could be wrong, that this valve DOES rotate to the appropriate next position but always in the forward direction.
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