I'm sorry but there is no wire connected to terminal 3. You may be confused by the terminal numbers which are, from left to right: E, N, L, 1, 2, 3, 4, 5, 6.Right I just checked the wires on the tiara and there is a wire connected to the 3rd terminal
E, N and L are correct, and also the link from L to 2 and 2 to 5.
Terminal 1 is HW ON (brown wire)
Terminal 3 is HW OFF and should be connected to the same terminal as the grey wire from the Drayton motorized valve
Terminal 4 is CH ON (uses the green yellow "earth wire", which is not recommended as it could cause confusion).
Connect a wire from Tiara terminal 3 (no 6, counting from the left) to the valve grey wire (in the Honeywell Junction box) and your problem should be solved. There should be three wires, including grey, connected to the same terminal.
What is the terminal strip for which is lying on top of the junction box?
The meter you show would do the trick.