That's what I'd like to know! You reckon your boiler and pump are both running and yet the water in the pipes is cool. Sorry but your system can't defy the first law of thermodynamics. Something is not happening in quite the way you think. Check this:
With CH only on demand (which you know doesn't work) does the boiler cycle on and off; mostly off? This means that the water isn't getting to the radiators. It's running round some short bypass loop and returning almost as hot as it went out. Maybe it never even gets out of the boiler! In these circumstances the boiler will go on and off on its own internal thermostat.
With HW only on demand, do the radiators get hot anyway? If they do then I can suggest a possible answer to this puzzle - the pipe leading out from the CH side of the three port valve is blocked.
Now how, I hear you ask, can the radiators get hot at all if their feed pipe is blocked? Here's how. With the HW flow open, hot water returning from the cylinder coil does not take the obvious route back to the boier, at least not all of it does. Due to poor pipe layout it shoots straight into the return pipe for the radiators on one floor and goes round these ones backwards. It arrives at the valve CH outlet which is closed/blocked and goes the correct way round the radiators on the other floor before finally returning to the boiler. I know this can happen because it happened to me!
With CH only on demand (which you know doesn't work) does the boiler cycle on and off; mostly off? This means that the water isn't getting to the radiators. It's running round some short bypass loop and returning almost as hot as it went out. Maybe it never even gets out of the boiler! In these circumstances the boiler will go on and off on its own internal thermostat.
With HW only on demand, do the radiators get hot anyway? If they do then I can suggest a possible answer to this puzzle - the pipe leading out from the CH side of the three port valve is blocked.
Now how, I hear you ask, can the radiators get hot at all if their feed pipe is blocked? Here's how. With the HW flow open, hot water returning from the cylinder coil does not take the obvious route back to the boier, at least not all of it does. Due to poor pipe layout it shoots straight into the return pipe for the radiators on one floor and goes round these ones backwards. It arrives at the valve CH outlet which is closed/blocked and goes the correct way round the radiators on the other floor before finally returning to the boiler. I know this can happen because it happened to me!