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I'd use White vinegar get a couple of gallons it's not dear and put that in leave it for a couple of hours then flush great stuff vinegar.
Thanks. I have not started yet. Been put off for the moment by comments about only persons certified to G3 may work on unvented systems.. I think I will have a go soon. It is only a matter of time before the scale will for sure cause a problem. Possible descalers are Fernox, white vinegar, ascorbic acid (vitamin C). I use ascorbic acid to descale my coffee maker and vinegar to descale my kettle. White vinegar would be much cheaper than Fernox so is a prime candidate. I will make sure that the heater vessel is well flushed out before switching the immersions on. The heater guarantee is void anyway as there is no record of any servicing. Oh and I will plug in a pressure relief valve as an added safety feature for future in the 3/4 inch BSP hot supply for the washing machine which is now redundant. Should anything happen to the Temp/Pressure relief valve that is part of the heater, this additional relief valve will kick in. I could go further and put in an expansion vessel too in the same leg of the hot supply.Never tried that before mate have you had much success ?