You really haven’t thought about that, have you?
I think we need clarification from @Yanni as to what he really wants. Maybe some of the above is a part of the solution.
What is so wrong with a PIR inside and the light outside? Admittedly, I didn't spend hours thinking about it.
If someone wants to exit via the fire escape for a cigarette, the light will only illuminate when they near the door. If it is the case that the heat from a fire might trigger the PIR, then the external light will come on anyway.